
Atmospheric entry into Titan's thick methane-nitrogen atmosphere generates an aerothermodynamic environment with peak heat flux levels in the range of 0.9 to 1.3 MW/m^2 and a substantial radiative contribution from the CN violet and red band systems, which together constitute one of the most demanding heat-shield design problems among foreseen planetary missions. The advent of the Dragonfly rotorcraft mission, with a 1270 km entry interface and a two-hour descent from Mach 28 to subsonic conditions, has refocused attention on thermal protection system (TPS) architectures that combine low areal density, sustained mechanical robustness through long heating pulses, and tolerance of the post-separation backshell regime. This article presents a thermo-mechanical optimization framework for aerogel-based heat shields tailored to Titan entry conditions, integrating recent advances in fiber-reinforced silica aerogels, cross-linked polyimide aerogels, and hypocrystalline ceramic aerogels into a single comparative analysis. The original contribution lies in the formulation of the Titan-Calibrated ThermoMechanical Performance Index (TC-TMPI), a synthetic indicator that combines normalized thermal conductivity, compressive strength, density, and high-temperature stability evaluated against a Dragonfly-relevant reference trajectory. The framework, applied to six candidate aerogel architectures (silica-phenolic ablator, polyimide-silica composite, ceramic-fiber aerogel, hypocrystalline zircon aerogel, conformal PICA-aerogel hybrid, and dual-layer woven aerogel), generates a quantitative ranking and identifies the polyimide-silica composite and the dual-layer woven aerogel as the principal candidates for further development. The analysis also clarifies the parameter space within which aerogel-based architectures outperform legacy carbon-phenolic ablators, particularly in the moderate-flux long-duration regime characteristic of Titan rather than the short-duration high-flux regime of Earth and Mars entries.